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Prof. Arik Yochelis,Department of Solar Energy and Environmental Physics, Ben-Gurion University of the Negev | The Racah Institute of Physics

Prof. Arik Yochelis,Department of Solar Energy and Environmental Physics, Ben-Gurion University of the Negev

Date: 
Wed, 14/05/201412:00-13:30
Location: 
Danciger B building, Seminar room
"The Challenging Spatiotemporal Properties of Ionic liquids: A Nonlinear Physics Perspective":
Studies of room temperature ionic liquids, showed that electrical diffuse layers in these highly concentrated electrolytes may exhibit spatially extended non-monotonic (oscillatory) and monotonic decays. These unconventional properties are fundamentally different from traditional (dilute) electrolytes and demonstrate the limited mechanistic understanding of the former. Moreover, electrolyte behavior placed in close proximity of two charged surfaces becomes even more unclear due to the possible overlap between diffuse layers. The latter is important as many applications require confinement into narrow spaces, e.g. energy and lubrication related applications.
To advance the understanding of electrical diffuse layers in highly concentrated electrolytes (and ionic liquids) we use a modified Poisson-Nernst-Planck equations and regulate weak dilutions. Using spatial dynamics methods and numerical computations, we analyze distinct diffuse layer characteristics (non-monotonic and monotonic) and provide for each type the analytic conditions and the validity limits in terms of applied voltage, domain size, molecular packing, and short range electrostatic correlations. We also discuss the qualitative generality of the results and thus believe that the insights will allow to advance the electrochemical understanding of confined highly concentrated electrolytes and their technological applications